
Frontiers in Marine Science | New and Recent Articles
Sequential extraction of carbonate-associated sulfate from calcite and dolomite in carbonate rocks
Carbonate-associated sulfate (CAS) serves as a crucial geochemical proxy for reconstructing ancient seawater chemistry and microbial activity. Traditional extraction methods using HCl often yield mixed isotopic signals from calcite and dolomite, complicating the analysis. This study introduces a sequential leaching approach utilizing 0.1 mol/L acetic acid for one hour, effectively isolating calcite-hosted CAS while minimizing dolomite dissolution. The findings reveal significant isotopic differences, with calcite-CAS showing ÎŽÂł4S values approximately 8.22â° higher than dolomite-CAS, enhancing the